عنوان
Synthesis and Spectral Study of a zinc(lI) Complex with NN\\
نویسنده (گان)
Kazem shoar,Reza; moeini,Keyvan ;Mardani,Zahra
چکیده مقاله
In this work, 2-(2-(2-hydroxyethylamino)ethylamino)cyclohexanol (L) was prepared in solvent by ring opening of epoxycyclohexane with 2-(2-aminoethylamino)ethanol and then its complex with zinc(II), [Zn(L)Cl2] were prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy and single-crystal X-Ray diffraction. The spectroscopies data revealed that the ligand acts as NN\\\'O-donor mode toward zinc atom and in agree with the structural analysis result. The X-ray analysis showed that the zinc atom has distorted trigonal bipyramidal geometry. In the crystal network of the complex there are intermolecular N–H···Cl, O–H···Cl and O–H···O hydrogen bonds, extending the crystal network in three directions.

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