عنوان
Synthesis and characterization of one manganese(II) coordination complex based on highly preorganized ligand PDA (1,10-phenanthroline-2,9 dicarboxylic acid.)
نویسنده (گان)
Gohari,Mahnaz;Mirzaei,Masoud;Hassanpoor,Azam
چکیده مقاله
The continuity of the searches for new materials with the higher performance than those used currently are necessary in order to satisfy daily improving technology. For this purpose, the sensible choice of suitable ligands with fixed geometry and flexible coordination capability plays a vital role for the design and synthesis of functional materials with interesting geometric configurations. In this respect, 1,10–phenanthroline as chelating nitrogen donor ligand has a rigid framework, and exhibits an excellent coordination ability with transition metal ions.¹,² Additionally, preorganized ligands have proven to be important in inorganic chemistry, biomedical, environmental, and industrial fields. ³ In this work, we have prepared one Mn(II) coordination compound by employing 1,10-phenanthroline-2,9-dicarboxylic acid (PDA) ligand, [Mn(PDA)(Cl)(H2O)]•H2O•EtOH (1) (Fig. 1). This complex has been characterized by melting point, elemental analysis and infrared spectroscopy (IR).

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